Using an in situ transmission electron microscopy (TEM) approach to investigate the growth mechanism of carbon nanotubes (CNTs) as well as the fabrication and properties of CNT-clamped metal atomic chains (MACs) is the focus of the research summarized in this thesis. The application of an in situ TEM approach in the above-mentioned research provides not only real-time observation but also monitored machining and structural evolvement at the atomic level. In this thesis, the author introduces a CNT tubular nano furnace that can be operated under TEM for investigation of the CNT nucleation mechanism. By studying the nucleation process of CNTs in the presence of various catalysts, including iron-based metallic catalysts and silicon oxide-based non-metallic catalysts, the physical states of the catalysts as well as the nucleation and growth process of CNTs are revealed. Based on the understanding of the nucleation mechanism, the author proposes a hetero-epitaxial growth strategy of CNTs from boron nitride, which provides a new route for the controllable growth of CNTs. In addition, the author presents an electron beam-assisted nanomachining technique and the fabrication of a CNT-clamped MAC prototype device based on this technique. The formation process of CNT-clamped Fe atomic chains (ACs) can be monitored with atomic resolution. The demonstrated quantized conductance and uninfluenced half-metallic properties of Fe ACs indicate that CNTs can be promising nanoscale electrodes or interconnectors for the linking and assembly of nano and subnano structures.
Using an in situ transmission electron microscopy (TEM) approach to investigate the growth mechanism of carbon nanotubes (CNTs) as well as the fabrication and properties of CNT-clamped metal atomic chains (MACs) is the focus of the research summarized in this thesis. The application of an in situ TEM approach in the above-mentioned research provides not only real-time observation but also monitored machining and structural evolvement at the atomic level. In this thesis, the author introduces a CNT tubular nano furnace that can be operated under TEM for investigation of the CNT nucleation mechanism. By studying the nucleation process of CNTs in the presence of various catalysts, including iron-based metallic catalysts and silicon oxide-based non-metallic catalysts, the physical states of the catalysts as well as the nucleation and growth process of CNTs are revealed. Based on the understanding of the nucleation mechanism, the author proposes a hetero-epitaxial growth strategy of CNTs from boron nitride, which provides a new route for the controllable growth of CNTs. In addition, the author presents an electron beam-assisted nanomachining technique and the fabrication of a CNT-clamped MAC prototype device based on this technique. The formation process of CNT-clamped Fe atomic chains (ACs) can be monitored with atomic resolution. The demonstrated quantized conductance and uninfluenced half-metallic properties of Fe ACs indicate that CNTs can be promising nanoscale electrodes or interconnectors for the linking and assembly of nano and subnano structures.
In xxxHolic Rei, Kimihiro Watanuki continues his relationship with the Space-Time Witch, Yuko. In her mysterious shop where wishes are granted - for a price - will he discover even more secrets? And what will he have to trade this time for the answers he seeks? The thrilling new instalment of a successful series that sees customers enter a mysterious shop somewhere in Tokyo. In it, their wishes may be granted. But always at a steep price. Beautifully seductive artwork and uniquely Japanese depictions of the supernatural will hypnotise Clamp fans and manga fans alike.
In xxxHolic Rei, Kimihiro Watanuki continues his relationship with the Space-Time Witch, Yuko. In her mysterious shop where wishes are granted - for a price - will he discover even more secrets? And what will he have to trade this time for the answers he seeks? The thrilling new instalment of a successful series that sees customers enter a mysterious shop somewhere in Tokyo. In it, their wishes may be granted. But always at a steep price. Beautifully seductive artwork and uniquely Japanese depictions of the supernatural will hypnotise Clamp fans and manga fans alike.
In xxxHolic Rei, Kimihiro Watanuki continues his relationship with the Space-Time Witch, Yuko. In her mysterious shop where wishes are granted - for a price - will he discover even more secrets? And what will he have to trade this time for the answers he seeks? The thrilling new instalment of a successful series that sees customers enter a mysterious shop somewhere in Tokyo. In it, their wishes may be granted. But always at a steep price. Beautifully seductive artwork and uniquely Japanese depictions of the supernatural will hypnotise Clamp fans and manga fans alike.
Kimihiro Watanuki is haunted by visions of ghosts and spirits. He seeks help from a mysterious woman named Yuko, who claims she can help. However, Watanuki must work for Yuko in order to pay for her aid. Soon Watanuki finds himself employed in Yuko's shop where he sees things and meets customers that are stranger than anything he could have ever imagined! Watanuki is Yuko's unwilling assistant, but even he is compelled by the fascinating adventures he's having since he started working for the 'space-time witch.'
Kimihiro Watanuki is haunted by visions of ghosts and spirits. He seeks help from a mysterious woman named Yuko, who claims she can help. However, Watanuki must work for Yuko in order to pay for her aid. Soon Watanuki finds himself employed in Yuko's shop where he sees things and meets customers that are stranger than anything he could have ever imagined! His shop grants people what they need, but there is always a price to be paid...
Kimihiro Watanuki is haunted by visions of ghosts and spirits. He seeks help from a mysterious woman named Yuko, who claims she can help. However, Watanuki must work for Yuko in order to pay for her aid. Soon Watanuki finds himself employed in Yuko's shop where he sees things and meets customers that are stranger than anything he could have ever imagined! His shop grants people what they need, but there is always a price to be paid...
Kimihiro Watanuki is haunted by visions of ghosts and spirits. He seeks advice from a mysterious woman named Yuko, who claims she can help. However, Watanuki must work for Yuko in order to pay for her aid. Soon Watanuki finds himself employed in Yuko's shop where he sees things and meets customers that are stranger than anything he could have ever imagined! Watanuki is Yuko's unwilling assistant, but even he is compelled by the fascinating adventures he's having since he started working for the space-time witch.''
Running from 2003-2009, Tsubasa was one of Clamp's most successful series - they are the collective also responsible for Magic Knight Rayearth (Dark Horse) and Cardcaptor Sakura (Dark Horse). This series features many of the characters from Clamp's equally popular xxxHOLiC (also available from Turnaround), which is also to be released as an omnibus later in the year by Kodansha Comics. This edition collects the first three Tsubasa stories, and is a charming and action-stuffed adventure, a must for manga fans of all ages.
Princess Sakura is under a terrible curse and Sayaoran will do whatever it takes to save her, even if it means journeying through space and time! Together with some strange companions, Sayaoran begins an epic quest through the universe to save the one he loves. Running from 2003-2009, Tsubasa was one of Clamp's most successful series; they are the collectively also responsible for Magic Knight Rayearth (Dark Horse) and Cardcaptor Sakura (Dark Horse). This edition collects the first three Tsubasa stories, and is a charming and action-stuffed adventure.
Princess Sakura is under a terrible curse and Sayaoran will do whatever it takes to save her. even if it means journeying through space and time! Together with some strange companions, Sayaoran begins an epic quest through the universe to save the one he loves. Running from 2003-2009, TSUBASA was one of Clamp's most successful series - they are the collective also responsible for Magic Knight Rayearth (Dark Horse) and Cardcaptor Sakura (Dark Horse).
Together with some strange companions, Sayaoran begins an epic quest through the universe to save the one he loves. Running from 2003-2009, Tsubasa was one of Clamp's most successful series - they are the collective also responsible for Magic Knight Rayearth (Dark Horse) and Cardcaptor Sakura (Dark Horse). This series features many of the characters from Clamp's equally popular xxxHOLiC (also available from Turnaround). This edition collects the next three Tsubasa stories, and is a charming and action-stuffed adventure, a must for manga fans of all ages.
Kimihiro Watanuki is haunted by visions of ghosts and spirits. He seeks help from a mysterious woman named Yuko, who claims she can help. However, Watanuki must work for Yuko in order to pay for her aid. Soon Watanuki finds himself employed in Yuko's shop where he sees things and meets customers that are stranger than anything he could have ever imagined!
Kimihiro Watanuki is haunted by visions of ghosts and spirits. He seeks help from a mysterious woman named Yuko, who claims she can help. Soon Watanuki finds himself employed in Yuko's shop where he sees things and meets customers that are stranger than anything he could have ever imagined! Watanuki is Yuko's unwilling assistant, but even he is compelled by the fascinating adventures he's having since he started working for the space-time witch.' Yuko operates a shop that grants people what they need, but there is always a price to be paid!'
In xxxHOLiC REI, Kimihiro Watanuki continues his relationship with the Space-Time Witch, Yuko. In her mysterious shop where wishes are granted - for a price - will he discover even more secrets? And what will he have to trade this time for the answers he seeks? The thrilling new instalment of a successful series that sees customers enter a mysterious shop somewhere in Tokyo. In it, their wishes may be granted. But always at a steep price. Beautifully seductive artwork and uniquely Japanese depictions of the supernatural will hypnotise CLAMP fans and manga fans alike.
The second half of Angelic Layer picks up where we left off -- with Misaki and Hikaru in a desperate fight against Kaede and Blanche But even getting out of the Layer intact means facing new rivals in the competition ahead, and facing the true, personal meaning of the game for Hikaru and her so faraway, so very close mother. The Angelic Layer saga concludes in Book Two
