G. K. Surya Prakash

The essential new edition of the book that put hypercarbon chemistry on the map A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks. Despite the firmly established tetravalency, carbon can bond simultaneously to five or more other atoms. "Hypercarbon" bonding permeates much organic, inorganic and organometallic chemistry, and the book serves as the compendium for this phenomenon. Copious diagrams illustrate the rich variety of hypercarbon structures now known, and patterns therein. Individual chapters deal with specific categories of compound (e.g. organometallics, carboranes, carbocations) or transformations that proceed through transient hypercarbon species, detailing fundamental chemistry, including reactivity, selectivity, stereochemistry, mechanistic factors and more.

Comprehensive and up-to-date coverage of onium ions—an indispensable reference for academic and industrial chemists In Onium Ions, Nobel Prize-winning chemist George Olah joins forces with coauthors Kenneth Laali, Qi Wang, and G. K. Surya Prakash to offer an in-depth look at the chemistry and reactions of these important electron-deficient compounds. While other texts have covered various individual types of onium ions, this work addresses the structure and chemistry of numerous different classes of onium ions. Contents include: *Discussions of well-established classes of onium ions, such as azonium, oxonium, sulfonium, selenonium, telluronium, and phosphonium ions. *Coverage of more recent types, from siliconium, halonium, and carbonium to carboxonium, carbosulfonium, and carbazonium ions. *Clear explanations of definition, classification, preparation, and chemistry of each major group of onium ions. *An exploration of superelectrophilic activation of onium ions through contact with superacid media. Enriched with numerous illustrations and a full listing of references for each chapter, Onium Ions should be a staple text in the professional chemist's library.

Written by Nobel prizewinner George Olah and his renowned co-workers, this is an in-depth yet concise overview of recent developments and significant progress in the field. As such, it covers all major C1compounds, such as carbon monoxide and carbon dioxide, methane and methanol, carbenes, C1 halides and organometallics.

Completely revised and updated, the third edition of this bestseller discusses the concept and ongoing development of using methanol and derived dimethyl ether as a transportation fuel, energy storage medium, and as a chemical raw material to replace fossil fuels. The contents have been expanded by 35% with new and up to date coverage on energy storage, methanol from biomass and waste products, as well as on carbon dioxide capture and recycling. Written by the late Nobel laureate George Olah, Alain Goeppert and G. K. Surya Prakash, this is an inspiring read for anyone concerned with the major challenge posed by environmental problems including global warming and ocean acidification due to massive increase in fossil fuel use. The book provides a comprehensive and sustainable solution to replace fossil fuels in the long run by chemical recycling of carbon dioxide through renewable methanol utilizing alternative energy sources such as solar, wind, hydro, geothermal and nuclear. The Methanol Economy is being progressively implemented in many parts of the world.

This book provides an unparalleled contemporary assessment of hydrocarbon chemistry – presenting basic concepts, current research, and future applications.• Comprehensive and updated review and discussion of the field of hydrocarbon chemistry• Includes literature coverage since the publication of the previous edition• Expands or adds coverage of: carboxylation, sustainable hydrocarbons, extraterrestrial hydrocarbons• Addresses a topic of special relevance in contemporary science, since hydrocarbons play a role as a possible replacement for coal, petroleum oil, and natural gas as well as their environmentally safe use• Reviews of prior edition: “...literature coverage is comprehensive and ideal for quickly reviewing specific topics...of most value to industrial chemists...” (Angewandte Chemie) and “...useful for chemical engineers as well as engineers in the chemical and petrochemical industries.” (Petroleum Science and Technology)

The chemistry of superacids has developed in the last two decades into a field of growing interest and importance. Now available in a new expanded second edition, this definitive work on superacids offers a comprehensive review of superacids and discusses the development of new superacid systems and applications of superacids in the promotion of unusual reactions. Covering Bronsted and Leurs superacids, solid superacids, carbocations, heterocations, and catalyzed reactions, this timely volume is invaluable to professionals, faculty, and graduate students in organic, inorganic, and physical chemistry.